---File Formats---

Files are numbered in the order in which the respective data appears in the Supplementary Information.
Each unique data set has a unique file number, thus identical data sets given in multiple file formats have the same number. 
From some total data sets, specfic data sets are given subsidary letters, e.g. for specific chromatograms from an HPLC-MS data set, which can be extrapolated from the original HPLC-MS file. 

Data are given in the following formats:
IR spectra: PerkinElmer (.sp) and comma-separated values (.csv).
NMR spectra: Jeol (.jdf).
Synthesised compound MS spectra: ASCII (.txt).
EPR spectra: ASCII (.txt).
CV spectra: Mathematical Programming System (.mps) and ASCII (.txt).
Absorbance spectra: Shimadzu (.bafx) and ASCII (.txt).
Radical trapping MS spectra: Bruker (.baf) and ASCII (.txt).


---Files---

Description of files:
000_file_description.txt

Methyl-2-(TEMPOmethyl)acrylate characterisation data:
001_methyl-2-(TEMPOmethyl)acrylate_IR.sp
001_methyl-2-(TEMPOmethyl)acrylate_IR.csv
002_methyl-2-(TEMPOmethyl)acrylate_NMR_1H.jdf
003_methyl-2-(TEMPOmethyl)acrylate_NMR_13C.jdf
004_methyl-2-(TEMPOmethyl)acrylate_NMR_COSY.jdf
005_methyl-2-(TEMPOmethyl)acrylate_NMR_DEPT.jdf
006_methyl-2-(TEMPOmethyl)acrylate_NMR_HMQC.jdf
007_methyl-2-(TEMPOmethyl)acrylate_MS.txt

2-(TEMPOmethyl)acrylic-acid characterisation data:
008_2-(TEMPOmethyl)acrylic-acid_IR.sp
008_2-(TEMPOmethyl)acrylic-acid_IR.csv
009_2-(TEMPOmethyl)acrylic-acid_NMR_1H.jdf
010_2-(TEMPOmethyl)acrylic-acid_NMR_13C.jdf
011_2-(TEMPOmethyl)acrylic-acid_NMR_COSY.jdf
012_2-(TEMPOmethyl)acrylic-acid_NMR_DEPT.jdf
013_2-(TEMPOmethyl)acrylic-acid_NMR_HMQC.jdf
014_2-(TEMPOmethyl)acrylic-acid_MS_pos.txt
015_2-(TEMPOmethyl)acrylic-acid_MS_neg.txt

CHANT characterisation data:
016_CHANT_IR.sp
016_CHANT_IR.csv
017_CHANT_NMR_1H.jdf
018_CHANT_NMR_13C.jdf
019_CHANT_NMR_COSY.jdf
020_CHANT_NMR_DEPT.jdf
021_CHANT_NMR_HMQC.jdf
022_CHANT_MS.txt

DEADANT characterisation data:
023_DEADANT_IR.sp
023_DEADANT_IR.csv
024_DEADANT_NMR_1H.jdf
025_DEADANT_NMR_13C.jdf
026_DEADANT_NMR_COSY.jdf
027_DEADANT_NMR_DEPT.jdf
028_DEADANT_NMR_HMQC.jdf
029_DEADANT_MS.txt

Trap free TEMPO concentration EPR data:
030_TEMPO_EPR.txt
031_CHANT_EPR.txt

Trap oxidation and reduction potential CV data:
032_CV.mps
032_CV.txt

Trap vulnerability to Michael addition NMR data:
033_Michael-addition_0-day.jdf
034_Michael-addition_1-day.jdf
035_Michael-addition_2-day.jdf
036_Michael-addition_4-day.jdf
037_Michael-addition_7-day.jdf
038_Michael-addition_14-day.jdf
039_Michael-addition_21-day.jdf

Trap blue LED absorbance data:
040_blue-LED-absorbance.bafx
040_blue-LED-absorbance.txt

CHANT MS calibration curve data:
041_CHANT_MS_0uM.baf
041_CHANT_MS_0uM.txt
042_CHANT_MS_0.01uM.baf
042_CHANT_MS_0.01uM.txt
043_CHANT_MS_0.01uM_background.baf
043_CHANT_MS_0.01uM_background.txt
044_CHANT_MS_0.025uM.baf
044_CHANT_MS_0.025uM.txt
045_CHANT_MS_0.025uM_background.baf
045_CHANT_MS_0.025uM_background.txt
046_CHANT_MS_0.05uM.baf
046_CHANT_MS_0.05uM.txt
047_CHANT_MS_0.05uM_background.baf
047_CHANT_MS_0.05uM_background.txt
048_CHANT_MS_0.075uM.baf
048_CHANT_MS_0.075uM.txt
049_CHANT_MS_0.075uM_background.baf
049_CHANT_MS_0.075uM_background.txt
050_CHANT_MS_0.1uM.baf
050_CHANT_MS_0.1uM.txt
051_CHANT_MS_0.1uM_background.baf
051_CHANT_MS_0.1uM_background.txt
052_CHANT_MS_0.25uM.baf
052_CHANT_MS_0.25uM.txt
053_CHANT_MS_0.25uM_background.baf
053_CHANT_MS_0.25uM_background.txt
054_CHANT_MS_0.5uM.baf
054_CHANT_MS_0.5uM.txt
055_CHANT_MS_0.5uM_background.baf
055_CHANT_MS_0.5uM_background.txt
056_CHANT_MS_0.75uM.baf
056_CHANT_MS_0.75uM.txt
057_CHANT_MS_0.75uM_background.baf
057_CHANT_MS_0.75uM_background.txt
058_CHANT_MS_1uM.baf
058_CHANT_MS_1uM.txt
059_CHANT_MS_1uM_background.baf
059_CHANT_MS_1uM_background.txt
060_CHANT_MS_2.5uM.baf
060_CHANT_MS_2.5uM.txt
061_CHANT_MS_2.5uM_background.baf
061_CHANT_MS_2.5uM_background.txt
062_CHANT_MS_5uM.baf
062_CHANT_MS_5uM.txt
063_CHANT_MS_5uM_background.baf
063_CHANT_MS_5uM_background.txt
064_CHANT_MS_7.5uM.baf
064_CHANT_MS_7.5uM.txt
065_CHANT_MS_7.5uM_background.baf
065_CHANT_MS_7.5uM_background.txt
066_CHANT_MS_10uM.baf
066_CHANT_MS_10uM.txt
067_CHANT_MS_10uM_background.baf
067_CHANT_MS_10uM_background.txt
068_CHANT_MS_25uM.baf
068_CHANT_MS_25uM.txt
069_CHANT_MS_25uM_background.baf
069_CHANT_MS_25uM_background.txt
070_CHANT_MS_50uM.baf
070_CHANT_MS_50uM.txt
071_CHANT_MS_50uM_background.baf
071_CHANT_MS_50uM_background.txt
072_CHANT_MS_75uM.baf
072_CHANT_MS_75uM.txt
073_CHANT_MS_75uM_background.baf
073_CHANT_MS_75uM_background.txt
074_CHANT_MS_100uM.baf
074_CHANT_MS_100uM.txt
075_CHANT_MS_100uM_background.baf
075_CHANT_MS_100uM_background.txt

CHANT-trapped-PhS MS calibration curve data:
076_CHANT-trapped-PhS_MS_0uM.baf
076_CHANT-trapped-PhS_MS_0uM.txt
077_CHANT-trapped-PhS_MS_0.01uM.baf
077_CHANT-trapped-PhS_MS_0.01uM.txt
078_CHANT-trapped-PhS_MS_0.01uM_background.baf
078_CHANT-trapped-PhS_MS_0.01uM_background.txt
079_CHANT-trapped-PhS_MS_0.025uM.baf
079_CHANT-trapped-PhS_MS_0.025uM.txt
080_CHANT-trapped-PhS_MS_0.025uM_background.baf
080_CHANT-trapped-PhS_MS_0.025uM_background.txt
081_CHANT-trapped-PhS_MS_0.05uM.baf
081_CHANT-trapped-PhS_MS_0.05uM.txt
082_CHANT-trapped-PhS_MS_0.05uM_background.baf
082_CHANT-trapped-PhS_MS_0.05uM_background.txt
083_CHANT-trapped-PhS_MS_0.075uM.baf
083_CHANT-trapped-PhS_MS_0.075uM.txt
084_CHANT-trapped-PhS_MS_0.075uM_background.baf
084_CHANT-trapped-PhS_MS_0.075uM_background.txt
085_CHANT-trapped-PhS_MS_0.1uM.baf
085_CHANT-trapped-PhS_MS_0.1uM.txt
086_CHANT-trapped-PhS_MS_0.1uM_background.baf
086_CHANT-trapped-PhS_MS_0.1uM_background.txt
087_CHANT-trapped-PhS_MS_0.25uM.baf
087_CHANT-trapped-PhS_MS_0.25uM.txt
088_CHANT-trapped-PhS_MS_0.25uM_background.baf
088_CHANT-trapped-PhS_MS_0.25uM_background.txt
089_CHANT-trapped-PhS_MS_0.5uM.baf
089_CHANT-trapped-PhS_MS_0.5uM.txt
090_CHANT-trapped-PhS_MS_0.5uM_background.baf
090_CHANT-trapped-PhS_MS_0.5uM_background.txt
091_CHANT-trapped-PhS_MS_0.75uM.baf
091_CHANT-trapped-PhS_MS_0.75uM.txt
092_CHANT-trapped-PhS_MS_0.75uM_background.baf
092_CHANT-trapped-PhS_MS_0.75uM_background.txt
093_CHANT-trapped-PhS_MS_1uM.baf
093_CHANT-trapped-PhS_MS_1uM.txt
094_CHANT-trapped-PhS_MS_1uM_background.baf
094_CHANT-trapped-PhS_MS_1uM_background.txt
095_CHANT-trapped-PhS_MS_2.5uM.baf
095_CHANT-trapped-PhS_MS_2.5uM.txt
096_CHANT-trapped-PhS_MS_2.5uM_background.baf
096_CHANT-trapped-PhS_MS_2.5uM_background.txt
097_CHANT-trapped-PhS_MS_5uM.baf
097_CHANT-trapped-PhS_MS_5uM.txt
098_CHANT-trapped-PhS_MS_5uM_background.baf
098_CHANT-trapped-PhS_MS_5uM_background.txt
099_CHANT-trapped-PhS_MS_7.5uM.baf
099_CHANT-trapped-PhS_MS_7.5uM.txt
100_CHANT-trapped-PhS_MS_7.5uM_background.baf
100_CHANT-trapped-PhS_MS_7.5uM_background.txt
101_CHANT-trapped-PhS_MS_10uM.baf
101_CHANT-trapped-PhS_MS_10uM.txt
102_CHANT-trapped-PhS_MS_10uM_background.baf
102_CHANT-trapped-PhS_MS_10uM_background.txt

Thiol-ene addition trapping MS data:
103_thiol-ene_standard.baf
103_thiol-ene_standard.txt
104_thiol-ene_standard_background.baf
104_thiol-ene_standard_background.txt
105_thiol-ene_trapless-control.baf
105_thiol-ene_trapless-control.txt
106_thiol-ene_trapless-control_background.baf
106_thiol-ene_trapless-control_background.txt
107_thiol-ene_pre-initiation.baf
107_thiol-ene_pre-initiation.txt
108_thiol-ene_pre-initiation_background.baf
108_thiol-ene_pre-initiation_background.txt
109_thiol-ene_post-trapping.baf
109_thiol-ene_post-trapping.txt
110_thiol-ene_post-trapping_background.baf
110_thiol-ene_post-trapping_background.txt

CHANT-trapped-PhS characterisation data:
111_CHANT-trapped-PhS_NMR_1H.jdf
112_CHANT-trapped-PhS_NMR_13C.jdf
113_CHANT-trapped-PhS_NMR_COSY.jdf
114_CHANT-trapped-PhS_NMR_DEPT.jdf
115_CHANT-trapped-PhS_NMR_HMQC.jdf
116_CHANT-trapped-PhS_MS.txt

N-chlorodibutylamine characterisation data for HLF trapping data:
117_N-chlorodibutylamine_NMR_1H.jdf
117_N-chlorodibutylamine_NMR_13C.jdf
117_N-chlorodibutylamine_NMR_COSY.jdf
117_N-chlorodibutylamine_NMR_DEPT.jdf
117_N-chlorodibutylamine_NMR_HMQC.jdf
118_N-chlorodibutylamine_MS.txt

HLF trapping MS data:
119_HLF_trapless-control.baf
119_HLF_trapless-control.txt
120_HLF_trapless-control_background.baf
120_HLF_trapless-control_background.txt
121_HLF_pre-initiation.baf
121_HLF_pre-initiation.txt
122_HLF_pre-initiation_background.baf
122_HLF_pre-initiation_background.txt
123_HLF_post-trapping.baf
123_HLF_post-trapping.txt
124_HLF_post-trapping_background.baf
124_HLF_post-trapping_background.txt

HLF trapping D2O exchange MS data:
125_HLF_D2O.baf
125_HLF_D2O.txt
126_HLF_D2O_background.baf
126_HLF_D2O_background.txt

HLF trapping tandem MS data:
127_HLF_tandem.baf
127_HLF_tandem.txt

Alkene ozonolysis trapping MS data:
128_alkene-ozonolysis_standard.baf
128_alkene-ozonolysis_standard.txt
129_alkene-ozonolysis_standard_background.baf
129_alkene-ozonolysis_standard_background.txt
130_alkene-ozonolysis_no-alkene.baf
130_alkene-ozonolysis_no-alkene.txt
131_alkene-ozonolysis_no-alkene_background.baf
131_alkene-ozonolysis_no-alkene_background.txt

Cyclohexene ozonolysis trapping MS data:
132_cyclohexene-ozonolysis_trapless-control.baf
132_cyclohexene-ozonolysis_trapless-control.txt
133_cyclohexene-ozonolysis_trapless-control_background.baf
133_cyclohexene-ozonolysis_trapless-control_background.txt
134_cyclohexene-ozonolysis_standard.baf
134_cyclohexene-ozonolysis_standard.txt
135_cyclohexene-ozonolysis_standard_background.baf
135_cyclohexene-ozonolysis_standard_background.txt
136_cyclohexene-ozonolysis_trapping-reaction.baf
136_cyclohexene-ozonolysis_trapping-reaction.txt
137_cyclohexene-ozonolysis_trapping-reaction_background.baf
137_cyclohexene-ozonolysis_trapping-reaction_background.txt

a-Pinene ozonolysis trapping MS data: 
138_a-pinene-ozonolysis_standard.baf
138_a-pinene-ozonolysis_standard.txt
139_a-pinene-ozonolysis_standard_background.baf
139_a-pinene-ozonolysis_standard_background.txt
140_a-pinene-ozonolysis_no-substrate.baf
140_a-pinene-ozonolysis_no-substrate.txt
141_a-pinene-ozonolysis_no-substrate_background.baf
141_a-pinene-ozonolysis_no-substrate_background.txt
142_a-pinene-ozonolysis_no-O2.baf
142_a-pinene-ozonolysis_no-O2.txt
143_a-pinene-ozonolysis_no-O2_background.baf
143_a-pinene-ozonolysis_no-O2_background.txt
144_a-pinene-ozonolysis_no-UV.baf
144_a-pinene-ozonolysis_no-UV.txt
145_a-pinene-ozonolysis_no-UV_background.baf
145_a-pinene-ozonolysis_no-UV_background.txt
146_a-pinene-ozonolysis_no-trap.baf
146_a-pinene-ozonolysis_no-trap.txt
147_a-pinene-ozonolysis_no-trap_background.baf
147_a-pinene-ozonolysis_no-trap_background.txt
148_a-pinene-ozonolysis_trapping-reaction-1.baf
148_a-pinene-ozonolysis_trapping-reaction-1.txt
149_a-pinene-ozonolysis_trapping-reaction-1_background.baf
149_a-pinene-ozonolysis_trapping-reaction-1_background.txt
150_a-pinene-ozonolysis_trapping-reaction-2.baf
150_a-pinene-ozonolysis_trapping-reaction-2.txt
151_a-pinene-ozonolysis_trapping-reaction-2_background.baf
151_a-pinene-ozonolysis_trapping-reaction-2_background.txt
152_a-pinene-ozonolysis_trapping-reaction-3.baf
152_a-pinene-ozonolysis_trapping-reaction-3.txt
153_a-pinene-ozonolysis_trapping-reaction-3_background.baf
153_a-pinene-ozonolysis_trapping-reaction-3_background.txt
154_a-pinene-ozonolysis_HPLC_chromatogram.baf
154a_a-pinene-ozonolysis_HPLC_chromatogram.txt
154b_a-pinene-ozonolysis_HPLC_trapped-R8_max.txt

a-Pinene ozonolysis trapping D2O exchange MS data:
155_a-pinene-ozonolysis_D-exchange_H2O.baf
155_a-pinene-ozonolysis_D-exchange_H2O.txt
156_a-pinene-ozonolysis_D-exchange_H2O_background.baf
156_a-pinene-ozonolysis_D-exchange_H2O_background.txt
157_a-pinene-ozonolysis_D-exchange_D2O.baf
157_a-pinene-ozonolysis_D-exchange_D2O.txt
158_a-pinene-ozonolysis_D-exchange_D2O_background.baf
158_a-pinene-ozonolysis_D-exchange_D2O_background.txt

a-Pinene ozonolysis trapping tandem MS data:
159_a-pinene-ozonolysis_tandem.baf
159_a-pinene-ozonolysis_tandem.txt

OH nonane degradation trapping with DEADANT MS data:
160_OH-nonane-degradation_HPLC_trapless-control_chromatogram.baf
160_OH-nonane-degradation_HPLC_trapless-control_chromatogram.txt
161_OH-nonane-degradation_HPLC_unreacted-trap-standard_chromatogram.baf
161_OH-nonane-degradation_HPLC_unreacted-trap-standard_chromatogram.txt
162_OH-nonane-degradation_HPLC_trapping-reaction_chromatogram.baf
162_OH-nonane-degradation_HPLC_trapping-reaction_chromatogram.txt

OH nonane degradation trapping with CHANT MS data:
163_OH-nonane-degradation_CHANT_HPLC_100-min-trapless-control_chromatogram.baf
163_OH-nonane-degradation_CHANT_HPLC_100-min-trapless-control_chromatogram.txt
164_OH-nonane-degradation_CHANT_HPLC_0-min-unreacted-trap-standard_chromatogram.baf
164_OH-nonane-degradation_CHANT_HPLC_0-min-unreacted-trap-standard_chromatogram.txt
165_OH-nonane-degradation_CHANT_HPLC_10-min-trapping-reaction_chromatogram.baf
165_OH-nonane-degradation_CHANT_HPLC_10-min-trapping-reaction_chromatogram.txt
166_OH-nonane-degradation_CHANT_HPLC_100-min-trapping-reaction_chromatogram.baf
166_OH-nonane-degradation_CHANT_HPLC_100-min-trapping-reaction_chromatogram.txt

OH nonane degradation trapping modelling data:
167_OH-nonane-degradation_gaseous-modelling-output.txt

Barton reaction trapping MS data:
168_Barton_trapless-control.baf
168_Barton_trapless-control.txt
169_Barton_trapless-control_background.baf
169_Barton_trapless-control_background.txt
170_Barton_pre-initiation.baf
170_Barton_pre-initiation.txt
171_Barton_pre-initiation_background.baf
171_Barton_pre-initiation_background.txt
172_Barton_post-trapping.baf
172_Barton_post-trapping.txt
173_Barton_post-trapping_background.baf
173_Barton_post-trapping_background.txt

Hunsdiecker reaction trapping MS data:
174_Hunsdiecker_trapless-control.baf
174_Hunsdiecker_trapless-control.txt
175_Hunsdiecker_trapless-control_background.baf
175_Hunsdiecker_trapless-control_background.txt
176_Hunsdiecker_pre-initiation.baf
176_Hunsdiecker_pre-initiation.txt
177_Hunsdiecker_pre-initiation_background.baf
177_Hunsdiecker_pre-initiation_background.txt
178_Hunsdiecker_post-trapping.baf
178_Hunsdiecker_post-trapping.txt
179_Hunsdiecker_post-trapping_background.baf
179_Hunsdiecker_post-trapping_background.txt

Decarboxylative aromatic iodination trapping MS data:
180_decarboxylative-aromatic-iodination_trapless-control.baf
180_decarboxylative-aromatic-iodination_trapless-control.txt
181_decarboxylative-aromatic-iodination_trapless-control_background.baf
181_decarboxylative-aromatic-iodination_trapless-control_background.txt
182_decarboxylative-aromatic-iodination_pre-initiation.baf
182_decarboxylative-aromatic-iodination_pre-initiation.txt
183_decarboxylative-aromatic-iodination_pre-initiation_background.baf
183_decarboxylative-aromatic-iodination_pre-initiation_background.txt
184_decarboxylative-aromatic-iodination_post-trapping.baf
184_decarboxylative-aromatic-iodination_post-trapping.txt
185_decarboxylative-aromatic-iodination_post-trapping_background.baf
185_decarboxylative-aromatic-iodination_post-trapping_background.txt
186_decarboxylative-aromatic-iodination_HPLC.baf
186a_decarboxylative-aromatic-iodination_HPLC_CHANT.txt
186b_decarboxylative-aromatic-iodination_HPLC_SR1-ART.txt
186c_decarboxylative-aromatic-iodination_HPLC_SR2-ART.txt
186d_decarboxylative-aromatic-iodination_HPLC_SR3-ART.txt

OH initiated methanol degradation trapping MS data:
187_OH-initiated-methanol-degradation_standard.baf
187_OH-initiated-methanol-degradation_standard.txt
188_OH-initiated-methanol-degradation_standard_background.baf
188_OH-initiated-methanol-degradation_standard_background.txt
189_OH-initiated-methanol-degradation_no-substrate.baf
189_OH-initiated-methanol-degradation_no-substrate.txt
190_OH-initiated-methanol-degradation_no-substrate_background.baf
190_OH-initiated-methanol-degradation_no-substrate_background.txt
191_OH-initiated-methanol-degradation_trapless-control.baf
191_OH-initiated-methanol-degradation_trapless-control.txt
192_OH-initiated-methanol-degradation_trapless-control_background.baf
192_OH-initiated-methanol-degradation_trapless-control_background.txt
193_OH-initiated-methanol-degradation_trapping-reaction.baf
193_OH-initiated-methanol-degradation_trapping-reaction.txt
194_OH-initiated-methanol-degradation_trapping-reaction_background.baf
194_OH-initiated-methanol-degradation_trapping-reaction_background.txt

OH initiated thymine degradation trapping MS data:
195_OH-initiated-thymine-degradation_trapless-control.baf
195_OH-initiated-thymine-degradation_trapless-control.txt
196_OH-initiated-thymine-degradation_trapless-control_background.baf
196_OH-initiated-thymine-degradation_trapless-control_background.txt
197_OH-initiated-thymine-degradation_standard.baf
197_OH-initiated-thymine-degradation_standard.txt
198_OH-initiated-thymine-degradation_standard_background.baf
198_OH-initiated-thymine-degradation_standard_background.txt
199_OH-initiated-thymine-degradation_trapping-reaction.baf
199_OH-initiated-thymine-degradation_trapping-reaction.txt
200_OH-initiated-thymine-degradation_trapping-reaction_background.baf
200_OH-initiated-thymine-degradation_trapping-reaction_background.txt

OH initiated glucose degradation trapping MS data:
201_OH-initiated-glucose-degradation_standard.baf
201_OH-initiated-glucose-degradation_standard.txt
202_OH-initiated-glucose-degradation_standard_background.baf
202_OH-initiated-glucose-degradation_standard_background.txt
203_OH-initiated-glucose-degradation_trapping-reaction.baf
203_OH-initiated-glucose-degradation_trapping-reaction.txt
204_OH-initiated-glucose-degradation_trapping-reaction_background.baf
204_OH-initiated-glucose-degradation_trapping-reaction_background.txt

OH initiated ascorbic acid degradation trapping MS data:
205_OH-initiated-ascorbic-acid-degradation_trapless-control.baf
205_OH-initiated-ascorbic-acid-degradation_trapless-control.txt
206_OH-initiated-ascorbic-acid-degradation_trapless-control_background.baf
206_OH-initiated-ascorbic-acid-degradation_trapless-control_background.txt
207_OH-initiated-ascorbic-acid-degradation_standard.baf
207_OH-initiated-ascorbic-acid-degradation_standard.txt
208_OH-initiated-ascorbic-acid-degradation_standard_background.baf
208_OH-initiated-ascorbic-acid-degradation_standard_background.txt
209_OH-initiated-ascorbic-acid-degradation_trapping-reaction.baf
209_OH-initiated-ascorbic-acid-degradation_trapping-reaction.txt
210_OH-initiated-ascorbic-acid-degradation_trapping-reaction_background.baf
210_OH-initiated-ascorbic-acid-degradation_trapping-reaction_background.txt